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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For CSe atoms 1 and 2

For CSe (Carbon monoselenide)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0002 0.0001 0.0002 0.0010 0.0031 0.0031 0.0032 0.0049 0.0049 0.0102 0.0077 -0.0002 0.0008 0.0057 0.0032 0.0012 0.0078 0.0041 0.0016 0.0081
MP3=FULL             0.0153                          
B2PLYP=FULL 0.0001 0.0000 0.0000 0.0004 0.0010 0.0010 0.0013 0.0015 0.0015 0.0032 0.0024 -0.0001 0.0003 0.0017   0.0004 0.0024   0.0005 0.0025
Quadratic configuration interaction QCISD(T)=FULL         0.0037   0.0037       0.0071   0.0011 0.0062   0.0017 0.0084   0.0019 0.0086
Coupled Cluster CCSD=FULL         0.0031         0.0093 0.0067 0.0001 0.0008 0.0055 0.0032 0.0012 0.0076 0.0039 0.0016 0.0078
CCSD(T)=FULL         0.0035           0.0070 0.0002 0.0010 0.0060 0.0031 0.0016 0.0080 0.0042 0.0018 0.0083
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ

cseq1.gif