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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For NH (Imidogen)

Energies in Hartree
Methods with standard basis sets
3-21G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ cc-pV(T+d)Z
Moller Plesset perturbation MP2=FULL -0.001570 -0.002646 -0.002786 -0.002953 -0.018010 -0.018155 -0.001857 -0.011751 -0.028017 -0.002003 -0.013287 -0.011751
MP3=FULL   -0.002535   -0.006938                
B2PLYP=FULL   -0.000776   -0.000863                
3-21G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ cc-pV(T+d)Z