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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For Br (Bromine atom)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.000000 -0.003182 -0.009774 -0.009986 -0.025630 -0.025630 -0.026256 -0.393380 -0.393380 -0.078723 -0.439454 -0.064978 -0.007427 -0.044061 -0.079928 -0.009301 -0.046503 -0.081079 -0.009763 -0.047126
MP3=FULL         -0.024316   -0.038876       -0.390702 -0.054385 -0.006515 -0.038063         -0.008604 -0.040788
MP4=FULL   -0.003044     -0.024999       -0.370023   -0.413439   -0.007042 -0.042227   -0.008930 -0.044609   -0.009380 -0.045205
B2PLYP=FULL 0.000000 -0.000961 -0.002990 -0.002919 -0.007838 -0.007847 -0.008030 -0.115467 -0.115467 -0.024328 -0.129045 -0.019336 -0.002298 -0.013282   -0.002866 -0.013993   -0.003006 -0.014174
Quadratic configuration interaction QCISD(T)=FULL         -0.024858   -0.025482       -0.407024   -0.006941 -0.040994   -0.008781 -0.043301   -0.009222 -0.043882
Coupled Cluster CCSD=FULL         -0.024364         -0.073725 -0.402939 -0.056969 -0.006611 -0.039414 -0.071486 -0.008357 -0.041673 -0.072564 -0.008779 -0.042246
CCSD(T)=FULL         -0.024839           -0.406862 -0.058636 -0.006934 -0.040914 -0.073440 -0.008764 -0.043214 -0.074531 -0.009204 -0.043794
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ