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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For CHCl2+ (dichloromethyl cation)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.000663 -0.010326 -0.025370 -0.006690 -0.025043 -0.025224 -0.026464 -0.116796 -0.117015 -0.049284 -0.213465 -0.071519 -0.014800 -0.082645 -0.153390 -0.017427 -0.090588 -0.156447 -0.018150 -0.093078
MP3=FULL         -0.023133   -0.024506       -0.208368 -0.070083 -0.013015 -0.079241         -0.016154 -0.089837
MP4=FULL   -0.009710     -0.023662       -0.117778   -0.211426   -0.013466 -0.081042   -0.016041 -0.089208   -0.016742 -0.091757
B2PLYP=FULL -0.000207 -0.003140 -0.007634 -0.002029 -0.007497 -0.007548 -0.007920 -0.033648 -0.033713 -0.014639 -0.061900 -0.020896 -0.004477 -0.024474   -0.005260 -0.026730   -0.005476 -0.027447
Quadratic configuration interaction QCISD(T)=FULL         -0.023494           -0.210799   -0.013327 -0.080665   -0.015870 -0.088797   -0.016569 -0.091340
Coupled Cluster CCSD=FULL         -0.022951         -0.044549 -0.208099 -0.069991 -0.012888 -0.078998 -0.149695 -0.015356 -0.087072 -0.152731 -0.016039 -0.089579
CCSD(T)=FULL         -0.023481           -0.210728 -0.071078 -0.013315 -0.080618 -0.152353 -0.015851 -0.088750 -0.155423 -0.016549 -0.091290
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ