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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For As+ (Arsenic cation)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.000226 -0.003535 -0.010255 -0.011861 -0.031545 -0.031545 -0.032205 -0.381531 -0.381531 -0.096789 -0.426353 -0.099822 -0.008618 -0.050254 -0.074780 -0.010264 -0.052679 -0.075433 -0.010670 -0.053323
MP3=FULL         -0.030895   -0.031546       -0.375874 -0.081332 -0.007783 -0.042834         -0.009601 -0.045473
MP4=FULL   -0.003463     -0.032212       -0.364261   -0.405954   -0.008473 -0.049109   -0.010113 -0.051433   -0.010514 -0.052045
B2PLYP=FULL -0.000080 -0.001073 -0.003217 -0.003563 -0.010102 -0.010102 -0.010297 -0.113854 -0.113854 -0.030813 -0.127203 -0.030061 -0.002739 -0.015420   -0.003244 -0.016134   -0.003369 -0.016323
Quadratic configuration interaction QCISD(T)=FULL         -0.031919           -0.396350   -0.008322 -0.046916   -0.009917 -0.049141   -0.010306 -0.049729
QCISD(TQ)=FULL         -0.031713   -0.032374       -0.394230   -0.008193 -0.045767 -0.067104 -0.009750 -0.047969 -0.067703 -0.010130 -0.048552
Coupled Cluster CCSD=FULL         -0.031030         -0.091104 -0.391041 -0.086869 -0.007916 -0.044925 -0.066273 -0.009427 -0.047120 -0.066866 -0.009797 -0.047701
CCSD(T)=FULL         -0.031878           -0.396044 -0.089186 -0.008307 -0.046771 -0.068325 -0.009897 -0.048993 -0.068925 -0.010284 -0.049580
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ