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All results from a given calculation for SiO (Silicon monoxide)

using model chemistry: HF/CEP-31G

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes C*V 1Σ
Energy calculated at HF/CEP-31G
 hartrees
Energy at 0K-19.375283
Energy at 298.15K 
HF Energy-19.375283
Nuclear repulsion energy8.195285
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at HF/CEP-31G
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 Σ 1207 1088 87.97 19.90 0.45 0.62

Unscaled Zero Point Vibrational Energy (zpe) 603.5 cm-1
Scaled (by 0.9014) Zero Point Vibrational Energy (zpe) 544.0 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at HF/CEP-31G
B
0.68975

See section I.F.4 to change rotational constant units
Geometric Data calculated at HF/CEP-31G

Point Group is C∞v

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
Si1 0.000 0.000 0.564
O2 0.000 0.000 -0.986

Atom - Atom Distances (Å)
  Si1 O2
Si11.5497
O21.5497

picture of Silicon monoxide state 1 conformation 1
More geometry information
Electronic energy levels

Electronic state

Charges, Dipole, Quadrupole and Polarizability
Charges from optimized geometry at HF/CEP-31G Charges (e)
Number Element Mulliken CHELPG AIM ESP
1 Si 0.783      
2 O -0.783      


Electric dipole moments
Electric dipole components in Debye
(What's a Debye? See section VII.A.3)
  x y z Total
  0.000 0.000 4.037 4.037
CHELPG        
AIM        
ESP        


Electric Quadrupole moment
Quadrupole components in D Å
Primitive
 xyz
x -15.058 0.000 0.000
y 0.000 -15.058 0.000
z 0.000 0.000 -22.414
Traceless
 xyz
x 3.678 0.000 0.000
y 0.000 3.678 0.000
z 0.000 0.000 -7.356
Polar
3z2-r2-14.713
x2-y20.000
xy0.000
xz0.000
yz0.000


Polarizabilities
Components of the polarizability tensor.
Units are Å3 (Angstrom cubed)
Change units.
  x y z
x 2.956 0.000 0.000
y 0.000 2.956 0.000
z 0.000 0.000 4.205


<r2> (average value of r2) Å2
<r2> 18.042
(<r2>)1/2 4.248