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All results from a given calculation for SCl2 (Sulfur dichloride)

using model chemistry: QCISD(T)/cc-pVDZ

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes C2V 1A1
Energy calculated at QCISD(T)/cc-pVDZ
 hartrees
Energy at 0K-1316.950906
Energy at 298.15K-1316.951184
HF Energy-1316.504720
Nuclear repulsion energy186.092191
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at QCISD(T)/cc-pVDZ
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 A1 498 474        
2 A1 197 187        
3 B2 494 471        

Unscaled Zero Point Vibrational Energy (zpe) 594.0 cm-1
Scaled (by 0.9531) Zero Point Vibrational Energy (zpe) 566.1 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at QCISD(T)/cc-pVDZ
ABC
0.45581 0.09217 0.07666

See section I.F.4 to change rotational constant units
Geometric Data calculated at QCISD(T)/cc-pVDZ

Point Group is C2v

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
S1 0.000 0.000 0.883
Cl2 0.000 1.617 -0.415
Cl3 0.000 -1.617 -0.415

Atom - Atom Distances (Å)
  S1 Cl2 Cl3
S12.07382.0738
Cl22.07383.2343
Cl32.07383.2343

picture of Sulfur dichloride state 1 conformation 1
More geometry information
Calculated Bond Angles
atom1 atom2 atom3 angle atom1 atom2 atom3 angle
Cl2 S1 Cl3 102.484
Electronic energy levels
Charges, Dipole, Quadrupole and Polarizability