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	hartrees
Energy at 0K	-1721.793742
Energy at 298.15K	-1721.794689
Nuclear repulsion energy	338.215677

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A₁	502	482	37.90
2	A₁	254	244	2.11
3	E	488	469	170.29
3	E	488	469	170.29
4	E	179	172	0.37
4	E	179	172	0.37

Atom	x (Å)	y (Å)	z (Å)
P1	0.000	0.000	0.724
Cl2	0.000	1.851	-0.213
Cl3	1.603	-0.926	-0.213
Cl4	-1.603	-0.926	-0.213
X5	0.000	0.000	1.724

	P1	Cl2	Cl3	Cl4	X5
P1		2.0747	2.0747	2.0747	1.0000
Cl2	2.0747		3.2063	3.2063	2.6791
Cl3	2.0747	3.2063		3.2063	2.6791
Cl4	2.0747	3.2063	3.2063		2.6791
X5	1.0000	2.6791	2.6791	2.6791

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
Cl2	P1	Cl3	101.200	Cl2	P1	Cl4	101.200
Cl2	P1	X5	116.839	Cl3	P1	Cl4	101.200
Cl3	P1	X5	116.839	Cl4	P1	X5	116.839

All results from a given calculation for PCl₃ (Phosphorus trichloride)

using model chemistry: B3PW91/6-31+G**

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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Number	Element	Mulliken
1	P	0.183
2	Cl	-0.061
3	Cl	-0.061
4	Cl	-0.061

	x	y	z	Total
	0.000	0.000	0.923	0.923
CHELPG
AIM
ESP

<r²>	216.988
(<r²>)^1/2	14.731

All results from a given calculation for PCl3 (Phosphorus trichloride)

using model chemistry: B3PW91/6-31+G**

States and conformations

All results from a given calculation for PCl₃ (Phosphorus trichloride)