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	hartrees
Energy at 0K	-839.299386
Energy at 298.15K
HF Energy	-838.110359
Nuclear repulsion energy	396.793411

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁'	765	741	0.00	15.47	0.00	0.00
2	A₁'	652	632	0.00	2.27	0.72	0.84
3	A₂"	962	933	399.18	0.00	0.00	0.00
4	A₂"	524	507	50.04	0.00	0.00	0.00
5	E'	1002	971	264.97	1.01	0.75	0.86
5	E'	1002	971	264.97	1.01	0.75	0.86
6	E'	485	470	41.04	0.53	0.75	0.86
6	E'	485	470	41.04	0.53	0.75	0.86
7	E'	162	157	0.15	0.30	0.75	0.86
7	E'	162	157	0.15	0.30	0.75	0.86
8	E"	459	445	0.00	0.89	0.75	0.86
8	E"	459	445	0.00	0.89	0.75	0.86

Atom	x (Å)	y (Å)	z (Å)
P1	0.000	0.000	0.000
F2	0.000	1.586	0.000
F3	1.374	-0.793	0.000
F4	-1.374	-0.793	0.000
F5	0.000	0.000	1.620
F6	0.000	0.000	-1.620

	P1	F2	F3	F4	F5	F6
P1		1.5863	1.5863	1.5863	1.6197	1.6197
F2	1.5863		2.7475	2.7475	2.2671	2.2671
F3	1.5863	2.7475		2.7475	2.2671	2.2671
F4	1.5863	2.7475	2.7475		2.2671	2.2671
F5	1.6197	2.2671	2.2671	2.2671		3.2394
F6	1.6197	2.2671	2.2671	2.2671	3.2394

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
F2	P1	F3	120.000	F2	P1	F4	120.000
F2	P1	F5	90.000	F2	P1	F6	90.000
F3	P1	F4	120.000	F3	P1	F5	90.000
F3	P1	F6	90.000	F4	P1	F5	90.000
F4	P1	F6	90.000	F5	P1	F6	180.000

All results from a given calculation for PF₅ (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/aug-cc-pVDZ

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF5 (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/aug-cc-pVDZ

States and conformations

All results from a given calculation for PF₅ (Phosphorus pentafluoride)