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	hartrees
Energy at 0K	-839.436496
Energy at 298.15K
HF Energy	-838.105062
Nuclear repulsion energy	408.853709

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁'	822	773	0.00	9.48	0.00	0.00
2	A₁'	676	635	0.00	1.23	0.75	0.85
3	A₂"	1022	960	347.30	0.00	0.00	0.00
4	A₂"	574	540	48.88	0.00	0.00	0.00
5	E'	1045	982	238.54	0.47	0.75	0.86
5	E'	1045	982	238.54	0.47	0.75	0.86
6	E'	539	507	35.94	0.45	0.75	0.86
6	E'	539	507	35.94	0.45	0.75	0.86
7	E'	171	161	0.25	0.21	0.75	0.86
7	E'	171	161	0.25	0.21	0.75	0.86
8	E"	510	479	0.00	0.77	0.75	0.86
8	E"	510	479	0.00	0.77	0.75	0.86

Atom	x (Å)	y (Å)	z (Å)
P1	0.000	0.000	0.000
F2	0.000	1.541	0.000
F3	1.334	-0.770	0.000
F4	-1.334	-0.770	0.000
F5	0.000	0.000	1.570
F6	0.000	0.000	-1.570

	P1	F2	F3	F4	F5	F6
P1		1.5406	1.5406	1.5406	1.5703	1.5703
F2	1.5406		2.6683	2.6683	2.1998	2.1998
F3	1.5406	2.6683		2.6683	2.1998	2.1998
F4	1.5406	2.6683	2.6683		2.1998	2.1998
F5	1.5703	2.1998	2.1998	2.1998		3.1406
F6	1.5703	2.1998	2.1998	2.1998	3.1406

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
F2	P1	F3	120.000	F2	P1	F4	120.000
F2	P1	F5	90.000	F2	P1	F6	90.000
F3	P1	F4	120.000	F3	P1	F5	90.000
F3	P1	F6	90.000	F4	P1	F5	90.000
F4	P1	F6	90.000	F5	P1	F6	180.000

All results from a given calculation for PF₅ (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/6-31G(2df,p)

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF5 (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/6-31G(2df,p)

States and conformations

All results from a given calculation for PF₅ (Phosphorus pentafluoride)