Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for SF₅Cl (sulfur chloropentafluoride)

using model chemistry: MP2=FULL/cc-pV(T+d)Z

States and conformations

Geometric Data calculated at MP2=FULL/cc-pV(T+d)Z

Point Group is C_4v

Cartesians (Å)

Atom	x (Å)	y (Å)	z (Å)
S1	0.000	0.000	-0.257
Cl2	0.000	0.000	1.785
F3	0.000	1.570	-0.273
F4	1.570	0.000	-0.273
F5	0.000	-1.570	-0.273
F6	-1.570	0.000	-0.273
F7	0.000	0.000	-1.822

Atom - Atom Distances (Å)

	S1	Cl2	F3	F4	F5	F6	F7
S1		2.0422	1.5702	1.5702	1.5702	1.5702	1.5652
Cl2	2.0422		2.5885	2.5885	2.5885	2.5885	3.6074
F3	1.5702	2.5885		2.2205	3.1403	2.2205	2.2059
F4	1.5702	2.5885	2.2205		2.2205	3.1403	2.2059
F5	1.5702	2.5885	3.1403	2.2205		2.2205	2.2059
F6	1.5702	2.5885	2.2205	3.1403	2.2205		2.2059
F7	1.5652	3.6074	2.2059	2.2059	2.2059	2.2059

More geometry information
Calculated Bond Angles

atom1	atom2	atom3	angle		atom1	atom2	atom3	angle
Cl2	S1	F3	90.575		Cl2	S1	F4	90.575
Cl2	S1	F5	90.575		Cl2	S1	F6	90.575
Cl2	S1	F7	180.000		F3	S1	F4	89.994
F3	S1	F5	178.850		F3	S1	F6	89.994
F3	S1	F7	89.425		F4	S1	F5	89.994
F4	S1	F6	178.850		F4	S1	F7	89.425
F5	S1	F6	89.994		F5	S1	F7	89.425
F6	S1	F7	89.425