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	hartrees
Energy at 0K	-540.363071
Energy at 298.15K
HF Energy	-539.739049
Nuclear repulsion energy	107.479808

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁	850	802	130.55	7.46	0.44	0.61
2	A₁	358	337	7.96	0.73	0.52	0.68
3	B₂	831	784	189.99	6.31	0.75	0.86

Atom	y (Å)	z (Å)
P1	0.000	0.567
F2	1.206	-0.473
F3	-1.206	-0.473

	P1	F2	F3
P1		1.5926	1.5926
F2	1.5926		2.4123
F3	1.5926	2.4123

All results from a given calculation for PF₂ (Phosphorus difluoride)

using model chemistry: MP2/6-311+G(3df,2p)

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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HF vs MP2 Bad vib. Calc. vs exp. 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All results from a given calculation for PF2 (Phosphorus difluoride)

using model chemistry: MP2/6-311+G(3df,2p)

States and conformations

All results from a given calculation for PF₂ (Phosphorus difluoride)