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All results from a given calculation for GaF3 (Gallium trifluoride)

using model chemistry: MP2/6-311G**

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes D3H 1A1'
Energy calculated at MP2/6-311G**
 hartrees
Energy at 0K-2222.401823
Energy at 298.15K 
HF Energy-2221.721184
Nuclear repulsion energy296.026235
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at MP2/6-311G**
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 A1' 665 632 0.00 8.54 0.06 0.11
2 A2" 209 199 72.90 0.00 0.00 0.00
3 E' 759 721 94.76 1.38 0.75 0.86
3 E' 759 721 94.76 1.38 0.75 0.86
4 E' 191 182 37.47 0.90 0.75 0.86
4 E' 191 182 37.47 0.90 0.75 0.86

Unscaled Zero Point Vibrational Energy (zpe) 1387.6 cm-1
Scaled (by 0.9502) Zero Point Vibrational Energy (zpe) 1318.5 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at MP2/6-311G**
ABC
0.19382 0.19382 0.09691

See section I.F.4 to change rotational constant units
Geometric Data calculated at MP2/6-311G**

Point Group is D3h

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
Ga1 0.000 0.000 0.000
F2 0.000 1.747 0.000
F3 1.513 -0.874 0.000
F4 -1.513 -0.874 0.000

Atom - Atom Distances (Å)
  Ga1 F2 F3 F4
Ga11.74701.74701.7470
F21.74703.02593.0259
F31.74703.02593.0259
F41.74703.02593.0259

picture of Gallium trifluoride state 1 conformation 1
More geometry information
Calculated Bond Angles
atom1 atom2 atom3 angle atom1 atom2 atom3 angle
F2 Ga1 F3 120.000 F2 Ga1 F4 120.000
F3 Ga1 F4 120.000
Electronic energy levels
Charges, Dipole, Quadrupole and Polarizability