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	hartrees
Energy at 0K	-927.210176
Energy at 298.15K
HF Energy	-926.614958
Nuclear repulsion energy	291.217686

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A'	2288	2172	0.00	710.39	0.00	0.01
2	A'	2275	2160	0.00	82.94	0.57	0.73
3	A'	1049	996	0.00	4.35	0.74	0.85
4	A'	993	943	0.00	6.54	0.75	0.86
5	A'	664	631	0.00	0.59	0.20	0.33
6	A'	490	465	0.00	17.23	0.05	0.10
7	A"	2279	2164	393.04	0.00	0.73	0.85
8	A"	977	927	193.72	0.00	0.75	0.86
9	A"	750	712	113.77	0.00	0.75	0.86
10	A"	167	159	0.39	0.00	0.75	0.86
11	A"	100	95	0.21	0.00	0.75	0.86
12	E'	2286	2170	246.08	61.75	0.75	0.86
12	E'	2286	2170	246.08	61.75	0.75	0.86
13	E'	2274	2159	56.23	1.30	0.75	0.86
13	E'	2274	2159	56.23	1.30	0.75	0.86
14	E'	1028	976	66.37	2.70	0.75	0.86
14	E'	1028	976	66.37	2.70	0.75	0.86
15	E'	1002	952	198.73	5.17	0.75	0.86
15	E'	1002	952	198.73	5.17	0.75	0.86
16	E'	967	918	651.87	8.42	0.75	0.86
16	E'	967	918	651.87	8.42	0.75	0.86
17	E'	703	668	1.02	7.77	0.75	0.86
17	E'	703	668	1.02	7.77	0.75	0.86
18	E'	172	163	0.61	0.10	0.75	0.86
18	E'	172	163	0.61	0.10	0.75	0.86
19	E"	2276	2161	0.00	111.65	0.75	0.86
19	E"	2276	2161	0.00	111.65	0.75	0.86
20	E"	973	924	0.00	14.87	0.75	0.86
20	E"	973	924	0.00	14.87	0.75	0.86
21	E"	703	667	0.00	7.82	0.75	0.86
21	E"	703	667	0.00	7.82	0.75	0.86
22	E"	83	79	0.00	0.20	0.75	0.86
22	E"	83	79	0.00	0.20	0.75	0.86

Atom	x (Å)	y (Å)	z (Å)
N1	0.000	0.000	0.000
Si2	0.000	1.747	0.000
Si3	-1.513	-0.874	0.000
Si4	1.513	-0.874	0.000
H5	-1.415	2.185	0.000
H6	-1.185	-2.318	0.000
H7	2.599	0.133	0.000
H8	0.681	2.287	1.198
H9	0.681	2.287	-1.198
H10	-2.321	-0.554	1.198
H11	-2.321	-0.554	-1.198
H12	1.640	-1.733	1.198
H13	1.640	-1.733	-1.198

	N1	Si2	Si3	Si4	H5	H6	H7	H8	H9	H10	H11	H12	H13
N1		1.7472	1.7472	1.7472	2.6028	2.6028	2.6028	2.6698	2.6698	2.6698	2.6698	2.6698	2.6698
Si2	1.7472		3.0262	3.0262	1.4808	4.2339	3.0600	1.4799	1.4799	3.4807	3.4807	4.0295	4.0295
Si3	1.7472	3.0262		3.0262	3.0600	1.4808	4.2339	4.0295	4.0295	1.4799	1.4799	3.4807	3.4807
Si4	1.7472	3.0262	3.0262		4.2339	3.0600	1.4808	3.4807	3.4807	4.0295	4.0295	1.4799	1.4799
H5	2.6028	1.4808	3.0600	4.2339		4.5082	4.5082	2.4160	2.4160	3.1234	3.1234	5.1103	5.1103
H6	2.6028	4.2339	1.4808	3.0600	4.5082		4.5082	5.1103	5.1103	2.4160	2.4160	3.1234	3.1234
H7	2.6028	3.0600	4.2339	1.4808	4.5082	4.5082		3.1234	3.1234	5.1103	5.1103	2.4160	2.4160
H8	2.6698	1.4799	4.0295	3.4807	2.4160	5.1103	3.1234		2.3962	4.1325	4.7769	4.1325	4.7769
H9	2.6698	1.4799	4.0295	3.4807	2.4160	5.1103	3.1234	2.3962		4.7769	4.1325	4.7769	4.1325
H10	2.6698	3.4807	1.4799	4.0295	3.1234	2.4160	5.1103	4.1325	4.7769		2.3962	4.1325	4.7769
H11	2.6698	3.4807	1.4799	4.0295	3.1234	2.4160	5.1103	4.7769	4.1325	2.3962		4.7769	4.1325
H12	2.6698	4.0295	3.4807	1.4799	5.1103	3.1234	2.4160	4.1325	4.7769	4.1325	4.7769		2.3962
H13	2.6698	4.0295	3.4807	1.4799	5.1103	3.1234	2.4160	4.7769	4.1325	4.7769	4.1325	2.3962

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
N1	Si2	H5	107.190	N1	Si2	H8	111.379
N1	Si2	H9	111.379	N1	Si3	H6	107.190
N1	Si3	H10	111.379	N1	Si3	H11	111.379
N1	Si4	H7	107.190	N1	Si4	H12	111.379
N1	Si4	H13	111.379	Si2	N1	Si3	120.000
Si2	N1	Si4	120.000	Si3	N1	Si4	120.000
H5	Si2	H8	109.380	H5	Si2	H9	109.380
H6	Si3	H10	109.380	H6	Si3	H11	109.380
H7	Si4	H12	109.380	H7	Si4	H13	109.380
H8	Si2	H9	108.109	H10	Si3	H11	108.109
H12	Si4	H13	108.109

All results from a given calculation for N(SiH₃)₃ (trisilylamine)

using model chemistry: MP2/cc-pVTZ

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for N(SiH3)3 (trisilylamine)

using model chemistry: MP2/cc-pVTZ

States and conformations

All results from a given calculation for N(SiH₃)₃ (trisilylamine)