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	hartrees
Energy at 0K	-537.264608
Energy at 298.15K
HF Energy	-536.948105
Nuclear repulsion energy	107.103043

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁	935	890	81.56	6.85	0.27	0.42
2	A₁	372	354	14.37	1.09	0.70	0.82
3	B₂	953	906	119.68	5.52	0.75	0.86

Atom	y (Å)	z (Å)
P1	0.000	0.562
F2	1.219	-0.468
F3	-1.219	-0.468

	P1	F2	F3
P1		1.5959	1.5959
F2	1.5959		2.4386
F3	1.5959	2.4386

All results from a given calculation for PF₂ (Phosphorus difluoride)

using model chemistry: MP2/3-21G*

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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HF vs MP2 Bad vib. Calc. vs exp. 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All results from a given calculation for PF2 (Phosphorus difluoride)

using model chemistry: MP2/3-21G*

States and conformations

All results from a given calculation for PF₂ (Phosphorus difluoride)