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	hartrees
Energy at 0K	-834.529223
Energy at 298.15K
HF Energy	-833.835968
Nuclear repulsion energy	404.089947

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁'	860	818	0.00	7.13	0.00	0.00
2	A₁'	744	708	0.00	1.44	0.75	0.86
3	A₂"	1105	1051	375.38	0.00	0.00	0.00
4	A₂"	576	548	73.23	0.00	0.00	0.00
5	E'	1128	1073	261.44	0.35	0.75	0.86
5	E'	1128	1073	261.44	0.35	0.75	0.86
6	E'	533	507	60.18	0.87	0.75	0.86
6	E'	533	507	60.18	0.87	0.75	0.86
7	E'	175	167	0.36	0.32	0.75	0.86
7	E'	175	167	0.36	0.32	0.75	0.86
8	E"	511	486	0.00	1.58	0.75	0.86
8	E"	511	486	0.00	1.58	0.75	0.86

Atom	x (Å)	y (Å)	z (Å)
P1	0.000	0.000	0.000
F2	0.000	1.560	0.000
F3	1.351	-0.780	0.000
F4	-1.351	-0.780	0.000
F5	0.000	0.000	1.587
F6	0.000	0.000	-1.587

	P1	F2	F3	F4	F5	F6
P1		1.5600	1.5600	1.5600	1.5869	1.5869
F2	1.5600		2.7020	2.7020	2.2253	2.2253
F3	1.5600	2.7020		2.7020	2.2253	2.2253
F4	1.5600	2.7020	2.7020		2.2253	2.2253
F5	1.5869	2.2253	2.2253	2.2253		3.1738
F6	1.5869	2.2253	2.2253	2.2253	3.1738

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
F2	P1	F3	120.000	F2	P1	F4	120.000
F2	P1	F5	90.000	F2	P1	F6	90.000
F3	P1	F4	120.000	F3	P1	F5	90.000
F3	P1	F6	90.000	F4	P1	F5	90.000
F4	P1	F6	90.000	F5	P1	F6	180.000

All results from a given calculation for PF₅ (Phosphorus pentafluoride)

using model chemistry: MP2/3-21G*

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF5 (Phosphorus pentafluoride)

using model chemistry: MP2/3-21G*

States and conformations

All results from a given calculation for PF₅ (Phosphorus pentafluoride)