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	hartrees
Energy at 0K	-540.750627
Energy at 298.15K
HF Energy	-540.601804
Nuclear repulsion energy	106.410740

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁	872	872	98.21	7.40	0.29	0.45
2	A₁	339	339	10.11	1.07	0.68	0.81
3	B₂	875	875	146.02	6.08	0.75	0.86

Atom	y (Å)	z (Å)
P1	0.000	0.567
F2	1.225	-0.472
F3	-1.225	-0.472

	P1	F2	F3
P1		1.6068	1.6068
F2	1.6068		2.4508
F3	1.6068	2.4508

All results from a given calculation for PF₂ (Phosphorus difluoride)

using model chemistry: B2PLYP=FULLultrafine/6-31G**

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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HF vs MP2 Bad vib. Calc. vs exp. 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All results from a given calculation for PF2 (Phosphorus difluoride)

using model chemistry: B2PLYP=FULLultrafine/6-31G**

States and conformations

All results from a given calculation for PF₂ (Phosphorus difluoride)