Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology | |
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Other names |
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Carbonothioic dichloride; Carbon chlorosulfide; Carbonic dichloride, thio-; Dichlorothiocarbonyl; Thiocarbonyl chloride; Thiocarbonyl dichloride; Phosgene, thio-; Thiocarbonic dichloride; Thiofosgen; Thiokarbonylchlorid; Dichlorothioformaldehyde; Carbonothioyl dichloride; |
INChI | INChIKey | SMILES | IUPAC name |
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InChI=1S/CCl2S/c2-1(3)4 | ZWZVWGITAAIFPS-UHFFFAOYSA-N | S=C(Cl)Cl | Carbonothioyl dichloride |
State | Conformation |
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1A1 | C2V |
Property | Value | Uncertainty | units | Reference | Comment |
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Mode Number | Symmetry | Frequency | Intensity | Comment | Description | ||||
---|---|---|---|---|---|---|---|---|---|
Fundamental(cm-1) | Harmonic(cm-1) | Reference | (km mol-1) | unc. | Reference | ||||
1 | A1 | 1137 | webbook | CS stretch | |||||
2 | A1 | 505 | webbook | CCl2 s-str | |||||
3 | A1 | 220 | webbook | CCl2 scissors | |||||
4 | B1 | 473 | webbook | renumbered (B1 B2 switch) | OOP | ||||
5 | B2 | 816 | webbook | renumbered (B1 B2 switch) | CCl2 a-str | ||||
6 | B2 | 294 | webbook | renumbered (B1 B2 switch) | CCl2 rock |
A | B | C | reference | comment |
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Product of moments of inertia | ||||
---|---|---|---|---|
amu3Å6 | 0 | gm3 cm6 |
Point Group C2v
Description | Value | unc. | Connectivity | Reference | Comment | |||
---|---|---|---|---|---|---|---|---|
Atom 1 | Atom 2 | Atom 3 | Atom 4 |
Atom | x (Å) | y (Å) | z (Å) |
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Bond descriptions
Bond Type | Count |
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C=S | 1 |
C-Cl | 2 |
Atom 1 | Atom 2 |
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C1 | S2 |
C1 | Cl3 |
C1 | Cl4 |
Energy (cm-1) | Degeneracy | reference | description |
---|---|---|---|
0 | 1 | 1A1 |
Ionization Energy | I.E. unc. | vertical I.E. | v.I.E. unc. | reference |
---|---|---|---|---|
9.680 | webbook |
State | Config | State description | Conf description | Exp. min. | Dipole (Debye) | Reference | comment | Point Group | Components | ||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
x | y | z | total | dipole | quadrupole | ||||||||
1 | 1 | 1A1 | C2v | True | 0.290 | NSRDS-NBS10 | DT | C2v | 1 | 2 |
State | Config | State description | Conf description | Exp. min. | Quadrupole (D Å) | Reference | comment | Point Group | Components | |||
---|---|---|---|---|---|---|---|---|---|---|---|---|
xx | yy | zz | dipole | quadrupole | ||||||||
1 | 1 | 1A1 | C2v | True | C2v | 1 | 2 |
alpha | unc. | Reference |
---|---|---|
9.573 | 0.519 | 2015Tha/Wu:144302 |
squib | reference | DOI |
---|---|---|
2015Tha/Wu:144302 | AJ Thakkar, T Wu "How well do static electronic dipole polarizabilities from gas-phase experiments compare with density functional and MP2 computations?" J. Chem. Phys. 143, 144302 (2015) | 10.1063/1.4932594 |
NSRDS-NBS10 | R. D. Nelson Jr., D. R. Lide, A. A. Maryott "Selected Values of electric dipole moments for molecules in the gas phase" NSRDS-NBS10, 1967 | 10.6028/NBS.NSRDS.10 |
webbook | NIST Chemistry Webbook (http://webbook.nist.gov/chemistry) | 10.18434/T4D303 |
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