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II.A.3. (XII.A.1.)

Listing of experimental geometry data for CCl2 (dichloromethylene)

Rotational Constants (cm-1)
See section I.F.4 to change rotational constant units
1.67558 0.12385 0.11532
Rotational Constants from 2002Dem/Mar:3282
Calculated rotational constants for CCl2 (dichloromethylene).

Point Group C2v

Internal coordinates (distances (r) in Å) (angles (a) in degrees) (dihedrals (d) in degrees)
Description Value Connectivity Reference Comment
Atom 1 Atom 2 Atom 3 Atom 4
rCCl 1.711 1 2 2002Dem/Mar:3282 re
aClCCl 109.22 2 1 3 2002Dem/Mar:3282 equilibrium
picture of dichloromethylene

Bond descriptions
Examples: C-C single bond, C=C, double bond, C#C triple bond, C:C aromatic bond
Bond Type Count
C-Cl 2

Atom x (Å) y (Å) z (Å)
C1 0.0000 0.0000 0.8424
Cl2 0.0000 1.3951 -0.1487
Cl3 0.0000 -1.3951 -0.1487

Atom - Atom Distances (Å)
  C1 Cl2 Cl3

Calculated geometries for CCl2 (dichloromethylene).

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