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Listing of experimental geometry data for GeH3Cl (monochlorogermane)

Rotational Constants (cm-1)


See section I.F.4 to change rotational constant units
A B C
  0.14455  
Rotational Constants from 1990Dem/Wlo:322-339
Calculated rotational constants for GeH3Cl (monochlorogermane).

Point Group C3v

Internal coordinates

(distances (r) in Å) (angles (a) in degrees) (dihedrals (d) in degrees)
Description Value Connectivity Reference Comment
Atom 1 Atom 2 Atom 3 Atom 4
rGeCl 2.145 1 2 1990Dem/Wlo:322-339 re
rGeH 1.516 1 3 1990Dem/Wlo:322-339 re
aHGeCl 107.107 2 1 3 1990Dem/Wlo:322-339
picture of monochlorogermane

Bond descriptions


Examples: C-C single bond, C=C, double bond, C#C triple bond, C:C aromatic bond
Bond Type Count
Cl-Ge 1
H-Ge 3
Atom x (Å) y (Å) z (Å)
Ge1 0.0000 0.0000 -0.6581
Cl2 0.0000 0.0000 1.4866
H3 0.0000 1.4485 -1.1040
H4 1.2545 -0.7243 -1.1040
H5 -1.2545 -0.7243 -1.1040

Atom - Atom Distances (Å)
  Ge1 Cl2 H3 H4 H5
Ge12.14471.51561.51561.5156
Cl22.14472.96812.96812.9681
H31.51562.96812.50892.5089
H41.51562.96812.50892.5089
H51.51562.96812.50892.5089

Calculated geometries for GeH3Cl (monochlorogermane).
References
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squib reference DOI
1990Dem/Wlo:322-339 J Demaison, G Wlodarczak, J Burie, H Bürger "The Rotational Spectrum of Germyl Chloride: Determination and Comparison of the Substitution, Double Substitution, and Equilibrium Structures" J. MOL. SPECT. 140, 322-339 (1990) 10.1016/0022-2852(90)90145-G

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