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Listing of experimental geometry data for FSN (Thiazyl fluoride)

Rotational Constants (cm-1)


See section I.F.4 to change rotational constant units
A B C
1.65847 0.29061 0.24660
Rotational Constants from NISTtriatomic
Calculated rotational constants for FSN (Thiazyl fluoride).

Point Group Cs

Internal coordinates

(distances (r) in Å) (angles (a) in degrees) (dihedrals (d) in degrees)
Description Value Connectivity Reference Comment
Atom 1 Atom 2 Atom 3 Atom 4
rNS 1.448 1 2 1967Coo/Kir:4521
rFS 1.643 1 3 1967Coo/Kir:4521
aNSF 116.92 2 1 3 1967Coo/Kir:4521
picture of Thiazyl fluoride

Bond descriptions


Examples: C-C single bond, C=C, double bond, C#C triple bond, C:C aromatic bond
Bond Type Count
S#N 1
F-S 1
Atom x (Å) y (Å) z (Å)
S1 0.0000 0.4258 0.0000
N2 1.4011 0.0601 0.0000
F3 -1.0897 -0.8038 0.0000

Atom - Atom Distances (Å)
  S1 N2 F3
S11.44801.6430
N21.44802.6364
F31.64302.6364

Calculated geometries for FSN (Thiazyl fluoride).
References
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squib reference DOI
1967Coo/Kir:4521 RL Cook, WH Kirchhoff "Further Investigations on the Microwave Spectrum of NSF: Evaluation of the Molecular Force Field, Centrifugal Distortion Constants, and the Dipole Moment" J. Chem. Phys. 47(11) 4521, 1967 10.1063/1.1701662
NISTtriatomic NIST Triatomic Spectral Database (http://www.physics.nist.gov/PhysRefData/MolSpec/Triatomic/index.html) 10.18434/T4DW2S

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