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Geometry for SF5 (Sulfur pentafluoride) 2A1 C4V

1910171554
InChI=1S/F5S/c1-6(2,3,4)5 INChIKey=HAQZDUWRNKKMQY-UHFFFAOYSA-N

B3LYP/6-31G


Point group is C4v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.2106   0.0000 0.0000 0.2106
F2 0.0000 0.0000 -1.5014   0.0000 0.0000 -1.5014
F3 0.0000 1.7908 0.2817   1.7908 0.0000 0.2817
F4 -1.7908 0.0000 0.2817   0.0000 -1.7908 0.2817
F5 0.0000 -1.7908 0.2817   -1.7908 0.0000 0.2817
F6 1.7908 0.0000 0.2817   0.0000 1.7908 0.2817
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5 F6
S1 1.7120 1.7922 1.7922 1.7922 1.7922
F2 1.7120 2.5271 2.5271 2.5271 2.5271
F3 1.7922 2.5271 2.5325 3.5815 2.5325
F4 1.7922 2.5271 2.5325 2.5325 3.5815
F5 1.7922 2.5271 3.5815 2.5325 2.5325
F6 1.7922 2.5271 2.5325 3.5815 2.5325
Maximum atom distance is 3.5815Å between atoms F3 and F5.
picture of Sulfur pentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 92.275 F2 S1 F4 92.275
F2 S1 F5 92.275 F2 S1 F6 92.275
F3 S1 F4 89.910 F3 S1 F5 175.451
F3 S1 F6 89.910 F4 S1 F5 89.910
F4 S1 F6 175.451 F5 S1 F6 89.910

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.