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Geometry for SF5Cl (sulfur chloropentafluoride) 1A1 C4V

1910171554
InChI=1S/ClF5S/c1-7(2,3,4,5)6 INChIKey=GSYNTTDHMKSMFY-UHFFFAOYSA-N

CID/6-31G*


Point group is C4v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 -0.2491   -0.2491 0.0000 0.0000
Cl2 0.0000 0.0000 1.7869   1.7869 0.0000 0.0000
F3 0.0000 1.5808 -0.2770   -0.2770 1.0317 1.1977
F4 1.5808 0.0000 -0.2770   -0.2770 1.1977 -1.0317
F5 0.0000 -1.5808 -0.2770   -0.2770 -1.0317 -1.1977
F6 -1.5808 0.0000 -0.2770   -0.2770 -1.1977 1.0317
F7 0.0000 0.0000 -1.8244   -1.8244 0.0000 0.0000
Atom - Atom Distances (Å)
  S1 Cl2 F3 F4 F5 F6 F7
S1 2.0360 1.5811 1.5811 1.5811 1.5811 1.5753
Cl2 2.0360 2.5998 2.5998 2.5998 2.5998 3.6113
F3 1.5811 2.5998 2.2356 3.1616 2.2356 2.2121
F4 1.5811 2.5998 2.2356 2.2356 3.1616 2.2121
F5 1.5811 2.5998 3.1616 2.2356 2.2356 2.2121
F6 1.5811 2.5998 2.2356 3.1616 2.2356 2.2121
F7 1.5753 3.6113 2.2121 2.2121 2.2121 2.2121
Maximum atom distance is 3.6113Å between atoms Cl2 and F7.
picture of sulfur chloropentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Cl2 S1 F3 91.014 Cl2 S1 F4 91.014
Cl2 S1 F5 91.014 Cl2 S1 F6 91.014
Cl2 S1 F7 180.000 F3 S1 F4 89.982
F3 S1 F5 177.973 F3 S1 F6 89.982
F3 S1 F7 88.986 F4 S1 F5 89.982
F4 S1 F6 177.973 F4 S1 F7 88.986
F5 S1 F6 89.982 F5 S1 F7 88.986
F6 S1 F7 88.986

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.