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Geometry for AsCl3 (Arsenous trichloride) 1A1 C3V

1910171554
1S/AsCl3/c2-1(3)4 INChIKey=OEYOHULQRFXULB-UHFFFAOYSA-N

B3LYP/3-21G*


Point group is C3v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
As1 0.0000 0.0000 0.6384   0.0000 0.0000 0.6384
Cl2 0.0000 1.9306 -0.4131   0.0000 1.9306 -0.4131
Cl3 1.6720 -0.9653 -0.4131   1.6720 -0.9653 -0.4131
Cl4 -1.6720 -0.9653 -0.4131   -1.6720 -0.9653 -0.4131
Atom - Atom Distances (Å)
  As1 Cl2 Cl3 Cl4
As1 2.1984 2.1984 2.1984
Cl2 2.1984 3.3440 3.3440
Cl3 2.1984 3.3440 3.3440
Cl4 2.1984 3.3440 3.3440
Maximum atom distance is 3.3440Å between atoms Cl2 and Cl3.
picture of Arsenous trichloride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Cl2 As1 Cl3 99.024 Cl2 As1 Cl4 99.024
Cl3 As1 Cl4 99.024

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.