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Geometry for HClO4 (perchloric acid) 1A CS

1910171554
InChI=1S/ClHO4/c2-1(3,4)5/h(H,2,3,4,5) INChIKey=VLTRZXGMWDSKGL-UHFFFAOYSA-N

HF/TZVP


Point group is Cs
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Cl1 -0.1282 0.0153 0.0000   0.1278 -0.0181 0.0000
O2 -0.4749 1.3843 0.0000   0.4445 -1.3944 0.0000
O3 1.4737 0.0638 0.0000   -1.4747 -0.0316 0.0000
O4 -0.4749 -0.6880 1.1863   0.4898 0.6774 1.1863
O5 -0.4749 -0.6880 -1.1863   0.4898 0.6774 -1.1863
H6 1.7866 -0.8369 0.0000   -1.7679 0.8758 0.0000
Atom - Atom Distances (Å)
  Cl1 O2 O3 O4 O5 H6
Cl1 1.4123 1.6026 1.4220 1.4220 2.0959
O2 1.4123 2.3538 2.3879 2.3879 3.1699
O3 1.6026 2.3538 2.4020 2.4020 0.9536
O4 1.4220 2.3879 2.4020 2.3727 2.5581
O5 1.4220 2.3879 2.4020 2.3727 2.5581
H6 2.0959 3.1699 0.9536 2.5581 2.5581
Maximum atom distance is 3.1699Å between atoms O2 and H6.
picture of perchloric acid
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
O2 Cl1 O3 102.476 O2 Cl1 O4 114.806
O2 Cl1 O5 114.806 O3 Cl1 O4 104.992
O3 Cl1 O5 104.992 O4 Cl1 O5 113.075
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Cl1 O3 H6 107.425

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.