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Geometry for SF5 (Sulfur pentafluoride) 2A1 C4V

1910171554
InChI=1S/F5S/c1-6(2,3,4)5 INChIKey=HAQZDUWRNKKMQY-UHFFFAOYSA-N

M06-2X/6-311G**


Point group is C4v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.2060   0.0000 0.0000 0.2060
F2 0.0000 0.0000 -1.3533   0.0000 0.0000 -1.3533
F3 0.0000 1.6242 0.2468   1.6242 0.0000 0.2468
F4 -1.6242 0.0000 0.2468   0.0000 -1.6242 0.2468
F5 0.0000 -1.6242 0.2468   -1.6242 0.0000 0.2468
F6 1.6242 0.0000 0.2468   0.0000 1.6242 0.2468
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5 F6
S1 1.5593 1.6247 1.6247 1.6247 1.6247
F2 1.5593 2.2799 2.2799 2.2799 2.2799
F3 1.6247 2.2799 2.2969 3.2483 2.2969
F4 1.6247 2.2799 2.2969 2.2969 3.2483
F5 1.6247 2.2799 3.2483 2.2969 2.2969
F6 1.6247 2.2799 2.2969 3.2483 2.2969
Maximum atom distance is 3.2483Å between atoms F3 and F5.
picture of Sulfur pentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 91.437 F2 S1 F4 91.437
F2 S1 F5 91.437 F2 S1 F6 91.437
F3 S1 F4 89.964 F3 S1 F5 177.126
F3 S1 F6 89.964 F4 S1 F5 89.964
F4 S1 F6 177.126 F5 S1 F6 89.964

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.