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Geometry for SF5 (Sulfur pentafluoride) 2A1 C4V

1910171554
InChI=1S/F5S/c1-6(2,3,4)5 INChIKey=HAQZDUWRNKKMQY-UHFFFAOYSA-N

M06-2X/aug-cc-pVDZ


Point group is C4v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.2090   0.0000 0.0000 0.2090
F2 0.0000 0.0000 -1.3685   0.0000 0.0000 -1.3685
F3 0.0000 1.6371 0.2492   1.6297 0.1549 0.2492
F4 -1.6371 0.0000 0.2492   0.1549 -1.6297 0.2492
F5 0.0000 -1.6371 0.2492   -1.6297 -0.1549 0.2492
F6 1.6371 0.0000 0.2492   -0.1549 1.6297 0.2492
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5 F6
S1 1.5775 1.6375 1.6375 1.6375 1.6375
F2 1.5775 2.3015 2.3015 2.3015 2.3015
F3 1.6375 2.3015 2.3151 3.2741 2.3151
F4 1.6375 2.3015 2.3151 2.3151 3.2741
F5 1.6375 2.3015 3.2741 2.3151 2.3151
F6 1.6375 2.3015 2.3151 3.2741 2.3151
Maximum atom distance is 3.2741Å between atoms F3 and F5.
picture of Sulfur pentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 91.408 F2 S1 F4 91.408
F2 S1 F5 91.408 F2 S1 F6 91.408
F3 S1 F4 89.965 F3 S1 F5 177.183
F3 S1 F6 89.965 F4 S1 F5 89.965
F4 S1 F6 177.183 F5 S1 F6 89.965

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.