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Geometry for AsCl3 (Arsenous trichloride) 1A1 C3V

1910171554
1S/AsCl3/c2-1(3)4 INChIKey=OEYOHULQRFXULB-UHFFFAOYSA-N

MP4/6-311G**


Point group is C3v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
As1 0.0000 0.0000 0.6369   0.0000 0.0000 0.6369
Cl2 0.0000 1.9268 -0.4121   0.0000 1.9268 -0.4121
Cl3 1.6687 -0.9634 -0.4121   1.6687 -0.9634 -0.4121
Cl4 -1.6687 -0.9634 -0.4121   -1.6687 -0.9634 -0.4121
Atom - Atom Distances (Å)
  As1 Cl2 Cl3 Cl4
As1 2.1939 2.1939 2.1939
Cl2 2.1939 3.3374 3.3374
Cl3 2.1939 3.3374 3.3374
Cl4 2.1939 3.3374 3.3374
Maximum atom distance is 3.3374Å between atoms Cl3 and Cl4.
picture of Arsenous trichloride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Cl2 As1 Cl3 99.038 Cl2 As1 Cl4 99.038
Cl3 As1 Cl4 99.038

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.