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Geometry for SO2F2 (Sulfuryl fluoride) 1A1 C2V

1910171554
InChI=1S/F2O2S/c1-5(2,3)4 INChIKey=OBTWBSRJZRCYQV-UHFFFAOYSA-N

QCISD/6-311G*


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.1752   0.1752 0.0000 0.0000
O2 0.0000 1.2594 0.8183   0.8183 1.2594 0.0000
O3 0.0000 -1.2594 0.8183   0.8183 -1.2594 0.0000
F4 1.1561 0.0000 -0.8831   -0.8831 0.0000 1.1561
F5 -1.1561 0.0000 -0.8831   -0.8831 0.0000 -1.1561
Atom - Atom Distances (Å)
  S1 O2 O3 F4 F5
S1 1.4141 1.4141 1.5674 1.5674
O2 1.4141 2.5187 2.4120 2.4120
O3 1.4141 2.5187 2.4120 2.4120
F4 1.5674 2.4120 2.4120 2.3123
F5 1.5674 2.4120 2.4120 2.3123
Maximum atom distance is 2.5187Å between atoms O2 and O3.
picture of Sulfuryl fluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
O2 S1 O3 125.894 O2 S1 F4 107.884
O2 S1 F5 107.884 O3 S1 F4 107.884
O3 S1 F5 107.884 F4 S1 F5 95.059

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.