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Geometry for Si(CH3)4 (tetramethylsilane) 1A1 TD

1910171554
InChI=1S/C4H12Si/c1-5(2,3)4/h1-4H3 INChIKey=CZDYPVPMEAXLPK-UHFFFAOYSA-N

B3PW91/cc-pVTZ


Point group is Td
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Si1 0.0000 0.0000 0.0000   0.0000 0.0000 0.0000
C2 1.0894 1.0894 1.0894   1.0540 -1.5544 -1.3819
C3 -1.0894 -1.0894 1.0894   1.1248 1.5544 1.3819
C4 -1.0894 1.0894 -1.0894   -1.0900 0.4306 -0.4843
C5 1.0894 -1.0894 -1.0894   -1.0887 -0.4306 0.4843
H6 1.7331 0.4856 1.7331   1.6974 -1.8294 -1.1300
H7 1.7331 1.7331 0.4856   0.4292 -2.4729 -2.1986
H8 0.4856 1.7331 1.7331   1.6967 -1.3363 -1.6846
H9 -1.7331 -1.7331 0.4856   0.5419 2.4729 2.1986
H10 -0.4856 -1.7331 1.7331   1.7696 1.3363 1.6846
H11 -1.7331 -0.4856 1.7331   1.7688 1.8294 1.1300
H12 -1.7331 0.4856 -1.7331   -1.7135 1.3285 0.2981
H13 -1.7331 1.7331 -0.4856   -0.4866 0.6850 -0.7705
H14 -0.4856 1.7331 -1.7331   -1.7541 -0.4516 -1.2845
H15 1.7331 -1.7331 -0.4856   -0.4845 -0.6850 0.7705
H16 0.4856 -1.7331 -1.7331   -1.7122 0.4516 1.2845
H17 1.7331 -0.4856 -1.7331   -1.7528 -1.3285 -0.2981
Atom - Atom Distances (Å)
  Si1 C2 C3 C4 C5 H6 H7 H8 H9 H10 H11 H12 H13 H14 H15 H16 H17
Si1 1.8869 1.8869 1.8869 1.8869 2.4987 2.4987 2.4987 2.4987 2.4987 2.4987 2.4987 2.4987 2.4987 2.4987 2.4987 2.4987
C2 1.8869 3.0812 3.0812 3.0812 1.0925 1.0925 1.0925 4.0371 3.2957 3.2957 4.0371 3.2957 3.2957 3.2957 4.0371 3.2957
C3 1.8869 3.0812 3.0812 3.0812 3.2957 4.0371 3.2957 1.0925 1.0925 1.0925 3.2957 3.2957 4.0371 3.2957 3.2957 4.0371
C4 1.8869 3.0812 3.0812 3.0812 4.0371 3.2957 3.2957 3.2957 4.0371 3.2957 1.0925 1.0925 1.0925 4.0371 3.2957 3.2957
C5 1.8869 3.0812 3.0812 3.0812 3.2957 3.2957 4.0371 3.2957 3.2957 4.0371 3.2957 4.0371 3.2957 1.0925 1.0925 1.0925
H6 2.4987 1.0925 3.2957 4.0371 3.2957 1.7644 1.7644 4.3005 3.1377 3.5998 4.9021 4.3005 4.3005 3.1377 4.3005 3.5998
H7 2.4987 1.0925 4.0371 3.2957 3.2957 1.7644 1.7644 4.9021 4.3005 4.3005 4.3005 3.5998 3.1377 3.5998 4.3005 3.1377
H8 2.4987 1.0925 3.2957 3.2957 4.0371 1.7644 1.7644 4.3005 3.5998 3.1377 4.3005 3.1377 3.5998 4.3005 4.9021 4.3005
H9 2.4987 4.0371 1.0925 3.2957 3.2957 4.3005 4.9021 4.3005 1.7644 1.7644 3.1377 3.5998 4.3005 3.5998 3.1377 4.3005
H10 2.4987 3.2957 1.0925 4.0371 3.2957 3.1377 4.3005 3.5998 1.7644 1.7644 4.3005 4.3005 4.9021 3.1377 3.5998 4.3005
H11 2.4987 3.2957 1.0925 3.2957 4.0371 3.5998 4.3005 3.1377 1.7644 1.7644 3.5998 3.1377 4.3005 4.3005 4.3005 4.9021
H12 2.4987 4.0371 3.2957 1.0925 3.2957 4.9021 4.3005 4.3005 3.1377 4.3005 3.5998 1.7644 1.7644 4.3005 3.1377 3.5998
H13 2.4987 3.2957 3.2957 1.0925 4.0371 4.3005 3.5998 3.1377 3.5998 4.3005 3.1377 1.7644 1.7644 4.9021 4.3005 4.3005
H14 2.4987 3.2957 4.0371 1.0925 3.2957 4.3005 3.1377 3.5998 4.3005 4.9021 4.3005 1.7644 1.7644 4.3005 3.5998 3.1377
H15 2.4987 3.2957 3.2957 4.0371 1.0925 3.1377 3.5998 4.3005 3.5998 3.1377 4.3005 4.3005 4.9021 4.3005 1.7644 1.7644
H16 2.4987 4.0371 3.2957 3.2957 1.0925 4.3005 4.3005 4.9021 3.1377 3.5998 4.3005 3.1377 4.3005 3.5998 1.7644 1.7644
H17 2.4987 3.2957 4.0371 3.2957 1.0925 3.5998 3.1377 4.3005 4.3005 4.3005 4.9021 3.5998 4.3005 3.1377 1.7644 1.7644
Maximum atom distance is 4.9021Å between atoms H6 and H12.
picture of tetramethylsilane
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
C2 Si1 C3 109.471 C2 Si1 C4 109.471
C2 Si1 C5 109.471 C3 Si1 C4 109.471
C3 Si1 C5 109.471 C4 Si1 C5 109.471
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Si1 C2 H6 111.182 Si1 C2 H7 111.182
Si1 C2 H8 111.182 Si1 C3 H9 111.182
Si1 C3 H10 111.182 Si1 C3 H11 111.182
Si1 C4 H12 111.182 Si1 C4 H13 111.182
Si1 C4 H14 111.182 Si1 C5 H15 111.182
Si1 C5 H16 111.182 Si1 C5 H17 111.182
H6 C2 H7 107.708 H6 C2 H8 107.708
H7 C2 H8 107.708 H9 C3 H10 107.708
H9 C3 H11 107.708 H10 C3 H11 107.708
H12 C4 H13 107.708 H12 C4 H14 107.708
H13 C4 H14 107.708 H15 C5 H16 107.708
H15 C5 H17 107.708 H16 C5 H17 107.708

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.