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Geometry for SF5 (Sulfur pentafluoride) 2A1 C4V

1910171554
InChI=1S/F5S/c1-6(2,3,4)5 INChIKey=HAQZDUWRNKKMQY-UHFFFAOYSA-N

SVWN/6-31G*


Point group is C4v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.2118   0.0000 0.0000 0.2118
F2 0.0000 0.0000 -1.3607   0.0000 0.0000 -1.3607
F3 0.0000 1.6295 0.2460   1.6295 0.0000 0.2460
F4 -1.6295 0.0000 0.2460   0.0000 -1.6295 0.2460
F5 0.0000 -1.6295 0.2460   -1.6295 0.0000 0.2460
F6 1.6295 0.0000 0.2460   0.0000 1.6295 0.2460
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5 F6
S1 1.5725 1.6299 1.6299 1.6299 1.6299
F2 1.5725 2.2884 2.2884 2.2884 2.2884
F3 1.6299 2.2884 2.3045 3.2591 2.3045
F4 1.6299 2.2884 2.3045 2.3045 3.2591
F5 1.6299 2.2884 3.2591 2.3045 2.3045
F6 1.6299 2.2884 2.3045 3.2591 2.3045
Maximum atom distance is 3.2591Å between atoms F3 and F5.
picture of Sulfur pentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 91.202 F2 S1 F4 91.202
F2 S1 F5 91.202 F2 S1 F6 91.202
F3 S1 F4 89.975 F3 S1 F5 177.595
F3 S1 F6 89.975 F4 S1 F5 89.975
F4 S1 F6 177.595 F5 S1 F6 89.975

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.