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Geometry for HClO4 (perchloric acid) 1A CS

1910171554
InChI=1S/ClHO4/c2-1(3,4)5/h(H,2,3,4,5) INChIKey=VLTRZXGMWDSKGL-UHFFFAOYSA-N

B2PLYP/6-31G*


Point group is Cs
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Cl1 0.1437 0.0077 0.0000   -0.1437 0.0081 0.0000
O2 -1.4999 0.0979 0.0000   1.4802 -0.2614 0.0000
O3 0.4748 1.3998 0.0000   -0.6252 -1.3394 0.0000
O4 0.4748 -0.7058 1.2088   -0.3947 0.7535 1.2088
O5 0.4748 -0.7058 -1.2088   -0.3947 0.7535 -1.2088
H6 -1.8399 -0.8198 0.0000   1.9186 0.6136 0.0000
Atom - Atom Distances (Å)
  Cl1 O2 O3 O4 O5 H6
Cl1 1.6461 1.4309 1.4422 1.4422 2.1493
O2 1.6461 2.3653 2.4509 2.4509 0.9787
O3 1.4309 2.3653 2.4279 2.4279 3.2070
O4 1.4422 2.4509 2.4279 2.4176 2.6138
O5 1.4422 2.4509 2.4279 2.4176 2.6138
H6 2.1493 0.9787 3.2070 2.6138 2.6138
Maximum atom distance is 3.2070Å between atoms O3 and H6.
picture of perchloric acid
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
O2 Cl1 O3 100.238 O2 Cl1 O4 104.853
O2 Cl1 O5 104.853 O3 Cl1 O4 115.352
O3 Cl1 O5 115.352 O4 Cl1 O5 113.896
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Cl1 O3 H6 32.822

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.