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Geometry for SF5 (Sulfur pentafluoride) 2A1 C4V

1910171554
InChI=1S/F5S/c1-6(2,3,4)5 INChIKey=HAQZDUWRNKKMQY-UHFFFAOYSA-N

B1B95/cc-pVDZ


Point group is C4v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.2085   0.0000 0.0000 0.2085
F2 0.0000 0.0000 -1.3749   0.0000 0.0000 -1.3749
F3 0.0000 1.6417 0.2510   1.6417 0.0000 0.2510
F4 -1.6417 0.0000 0.2510   0.0000 -1.6417 0.2510
F5 0.0000 -1.6417 0.2510   -1.6417 0.0000 0.2510
F6 1.6417 0.0000 0.2510   0.0000 1.6417 0.2510
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5 F6
S1 1.5834 1.6423 1.6423 1.6423 1.6423
F2 1.5834 2.3106 2.3106 2.3106 2.3106
F3 1.6423 2.3106 2.3218 3.2835 2.3218
F4 1.6423 2.3106 2.3218 2.3218 3.2835
F5 1.6423 2.3106 3.2835 2.3218 2.3218
F6 1.6423 2.3106 2.3218 3.2835 2.3218
Maximum atom distance is 3.2835Å between atoms F3 and F5.
picture of Sulfur pentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 91.482 F2 S1 F4 91.482
F2 S1 F5 91.482 F2 S1 F6 91.482
F3 S1 F4 89.962 F3 S1 F5 177.035
F3 S1 F6 89.962 F4 S1 F5 89.962
F4 S1 F6 177.035 F5 S1 F6 89.962

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.