Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All data (experiment and calculated) in the CCCBDB for PF₂⁺ (Phosphorus difluoride cation)

Property		Experiment	Calculated	Comparison
Energies Entropies	Enthalpy 298.15K
	Enthalpy 0K
	Energy 0K		571
	Energy 298.15K		10
	Atomization Enthalpy 298.15K		0
	Atomization Enthalpy 0K		0
	Entropy (298.15K)	x	0	x
	Entropy at any temperature		0
	Integrated Heat Capacity		0
	Heat Capacity (Cp)		0
	Nuclear Repulsion Energy		572
	HOMO-LUMO Energies		521
	Barriers to Internal Rotation		0
Geometries	Cartesians		572
	Internal Coordinates		14
	Products of moments of inertia		564
	Rotational Constants		572
	Point Group		573
Vibrations	Vibrational Frequencies	fun.	572	x
	Vibrational Intensities		521
	Zero-point energies		572
	Vibrational scaling factors
	Anharmonic frequencies and constants
	Raman frequencies and intensities		421
Electronic States	Electronic states	x	0
Electrostatics	Atom charges		343
	Dipole		491
	Quadrupole		400
	Polarizability		410
Other results	Spin		0
	Number of basis functions		70
	Conformations		1