Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology | |
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You are here: Calculated > Vibrations > Bad Calculations > Bad vib. Calc. vs exp. OR Resources > Bad Calculations > Vibrations > Bad vib. Calc. vs exp. |
Calculated frequencies that differ from experiment by more than 400 cm-1 or have a ratio with experiment outside of 0.7 to 1.2 are listed
Calculated vibrational frequencies ("theory" in table) are calculated at
LSDA/SDD
Calculated values were scaled by 1.
Species | Name | mode | int rot | Symmetry | Experiment | Theory | difference | ratio |
---|---|---|---|---|---|---|---|---|
SO2 | Sulfur dioxide | 1 | A1 | 1151 | 895 | -256 | 1.286 | |
SO2 | Sulfur dioxide | 2 | A1 | 518 | 389 | -129 | 1.332 | |
SO2 | Sulfur dioxide | 3 | B2 | 1362 | 983 | -379 | 1.385 | |
NH3 | Ammonia | 2 | torsion | A1 | 950 | 253 | -697 | 3.754 |
AlF3 | Aluminum trifluoride | 4 | E' | 263 | 218 | -45 | 1.209 |