return to home page Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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Bad vibrational frequency predictions

19 02 11 15 45

Calculated frequencies that differ from experiment by more than 400 cm-1 or have a ratio with experiment outside of 0.7 to 1.2 are listed

Calculated vibrational frequencies ("theory" in table) are calculated at HSEh1PBE/SDD
Calculated values were scaled by 1.

Species Name mode int rot Symmetry Experiment Theory difference ratio
SO2 Sulfur dioxide 1 A1 1151 936 -215 1.230
SO2 Sulfur dioxide 2 A1 518 413 -104 1.252
SO2 Sulfur dioxide 3 B2 1362 1034 -327 1.316
NH3 Ammonia 2 torsion A1 950 371 -579 2.558
NH3 Ammonia 3 E 3444 3854 410 0.894