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Compare vibrational frequencies in CCCBDB for C5H8 (Cyclopentene)

B3LYP/6-311+G(3df,2p)

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A' 3189 3084   18 A'   3066  
2 A' 3085 2984   26 A'   2958  
3 A' 3051 2950   34 A'   2916  
4 A' 3031 2931   29 A'   2902  
5 A' 2992 2893   41 A'   2852  
6 A' 1674 1619   3 A'   1616  
7 A' 1510 1460   -7 A'   1467  
8 A' 1486 1437   -12 A'   1449  
9 A' 1326 1282   -20 A'   1302  
10 A' 1230 1190   -94 A'   1284  
11 A' 1132 1095   -118 A'   1213  
12 A' 1069 1034   -14 A'   1048  
13 A' 971 939   -25 A'   964  
14 A' 901 872   -90 A'   962  
15 A' 819 792   -112 A'   904  
16 A' 715 691   -1 A'   692  
17 A' 616 596   -7 A'   603  
18 A' 139 135   -119 A'   254  
19 A" 3164 3060   21 A"   3039  
20 A" 3040 2939   -28 A"   2967  
21 A" 2994 2895   -32 A"   2927  
22 A" 1491 1442   -25 A"   1467  
23 A" 1381 1336   -96 A"   1432  
24 A" 1319 1276   -80 A"   1356  
25 A" 1310 1267   -35 A"   1302  
26 A" 1224 1183   -114 A"   1297  
27 A" 1152 1114   -93 A"   1207  
28 A" 1033 999   -114 A"   1113  
29 A" 980 947   -135 A"   1082  
30 A" 916 885   -52 A"   937  
31 A" 889 860   60 A"   800  
32 A" 784 758   56 A"   702  
33 A" 393 380   -7 A"   387  
The calculated vibrational frequencies were scaled by 0.967

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.