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Compare vibrational frequencies in CCCBDB for H2CNCN (cyanamide, methylene)

MP4/6-31G*

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A' 3235 3089   -48 A'   3137  
2 A' 3111 2970   762 A'   2208  
3 A' 2153 2056   435 A'   1621  
4 A' 1663 1588   132 A'   1456  
5 A' 1506 1438           
6 A' 1239 1183   -32 A'   1215  
7 A' 925 883           
8 A' 602 575           
9 A' 236 225           
10 A" 1069 1020   -70 A"   1090  
11 A" 767 732           
12 A" 337 322           
The calculated vibrational frequencies were scaled by 0.9548

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.