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Compare vibrational frequencies in CCCBDB for H2CNCN (cyanamide, methylene)

B2PLYP=FULL/3-21G

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A' 3235 3080   -57 A'   3137  
2 A' 3110 2961   753 A'   2208  
3 A' 2197 2092   471 A'   1621  
4 A' 1661 1581   125 A'   1456  
5 A' 1544 1470           
6 A' 1243 1184   -31 A'   1215  
7 A' 889 846           
8 A' 611 581           
9 A' 260 248           
10 A" 1116 1062   -28 A"   1090  
11 A" 797 759           
12 A" 400 381           
The calculated vibrational frequencies were scaled by 0.952

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.