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Compare vibrational frequencies in CCCBDB for H2CNCN (cyanamide, methylene)

B2PLYP=FULL/cc-pVDZ

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A' 3234 3099   -38 A'   3137  
2 A' 3103 2974   766 A'   2208  
3 A' 2247 2154   533 A'   1621  
4 A' 1685 1615   159 A'   1456  
5 A' 1489 1427           
6 A' 1222 1171   -44 A'   1215  
7 A' 950 911           
8 A' 620 594           
9 A' 249 239           
10 A" 1084 1039   -51 A"   1090  
11 A" 776 744           
12 A" 367 351           
The calculated vibrational frequencies were scaled by 0.9585

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.