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Compare vibrational frequencies in CCCBDB for C2H4+ (Ethylene cation)

HF/6-311G**

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 Ag 3295 2994           
2 Ag 1692 1537   49 Ag   1488  
3 Ag 1366 1241   -18 Ag   1259  
4 Au 375 341   257 Au   84  
5 B1u 3284 2984           
6 B1u 1583 1438           
7 B2g 1196 1087   186 B3u   901  
8 B2u 3416 3104   2001 B2g   1103  
9 B2u 900 818           
10 B3g 3402 3091   2278 B2u   813  
11 B3g 1331 1209   -1769 B1u   2979  
12 B3u 1079 980   -432 B1u   1412  
The calculated vibrational frequencies were scaled by 0.9085

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.