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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For GaS atoms 1 and 2

For GaS (Gallium monosulfide)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0009 0.0002 0.0012 0.0011 0.0079 0.0079 0.0085 0.0134 0.0134 0.0205 0.0177 -0.0016 0.0015 0.0082 0.0106 0.0021 0.0087 0.0142 0.0026 0.0100
B2PLYP=FULL 0.0009 0.0002 0.0007 0.0016 0.0047 0.0047 0.0048 0.0077 0.0077 0.0101 0.0104 -0.0005 0.0007 0.0043   0.0010 0.0042   0.0012 0.0048
Quadratic configuration interaction QCISD(T)=FULL         0.0098           0.0212   0.0020 0.0102   0.0027 0.0105   0.0033 0.0124
Coupled Cluster CCSD=FULL         0.0089         0.0271 0.0209 -0.0026 0.0018 0.0100 0.0113 0.0026 0.0110 0.0155 0.0033 0.0127
CCSD(T)=FULL         0.0097           0.0209 -0.0026 0.0018 0.0100 0.0108 0.0027 0.0102 0.0144 0.0033 0.0121
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ

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