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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For ArH+ atoms 1 and 2

For ArH+ (Argon hydride cation)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ aug-cc-pCVTZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0001 -0.0002 -0.0000 -0.0000 0.0000 0.0013 0.0013 0.1510 0.0000 0.0018 0.0006 0.0002 0.0013 0.0000 0.0019 0.0012 0.1630 0.0022 0.0013 0.0012 0.0022
MP3=FULL         -0.1613   0.0000       0.0006 0.0000 0.0013 0.0013         0.0013 0.0012 0.0022
MP4=FULL   -0.0002     0.0000       -0.0001   0.0005   0.0013 0.0012   0.0012 0.0027   0.0012 0.0011 0.0021
B2PLYP=FULL 0.0000 0.0001 -0.0000 -0.0000 0.0001 0.0004 0.0007 -0.0001 0.0001 0.0006 0.0002 0.0000 0.0004 0.1541   0.0004 0.0008   0.0004 0.0004 0.0006
Quadratic configuration interaction QCISD(T)=FULL         0.0001           0.0005   0.0013 0.0012   0.0012 0.0027   0.0012 0.0011 0.0021
Coupled Cluster CCSD=FULL         0.0001         0.0018 0.0007 0.0000 0.0013 0.0013 0.0019 0.0012 0.0028 0.0022 0.0015 0.0012 0.0022
CCSD(T)=FULL         0.0001           0.0005 -0.0000 0.0013 0.0012 0.0018 0.0012 0.0027 0.0021 0.0012 0.0011 0.0021
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ aug-cc-pCVTZ daug-cc-pVDZ daug-cc-pVTZ

arhq1.gif