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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For GeC atoms 1 and 2

For GeC (Germanium monocarbide)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0020 0.0009 0.0012 0.0049 0.0075 0.0107 0.0109 0.0174 0.0174 0.0199 0.0226 0.0003 0.0015 0.0115 0.0189 0.0028 0.0187 0.0259 0.0041 0.0203
MP3=FULL         0.0942   0.0191                          
B2PLYP=FULL 0.2161 0.0008 0.0007 0.0020 0.0032 0.0032 0.0030 0.0049 0.0049 0.0055 0.0055 0.0003 0.0000     0.0009     0.0009 0.0043
Quadratic configuration interaction QCISD(T)=FULL         0.0068           0.0148   0.0011 0.0082     0.0127   0.0031 0.0148
Coupled Cluster CCSD=FULL                   0.0153 0.0137 -0.0009     0.0133 0.0024 0.0133 0.0178 0.0029 0.0151
CCSD(T)=FULL         0.0096           0.0146 -0.0008 0.0012 0.0080 0.0121 0.0023 0.0130 0.0174 0.0030 0.0151
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ

gec.gif