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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For BeH+ atoms 1 and 2

For BeH+ (beryllium monohydride cation)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVQZ
Moller Plesset perturbation MP2=FULL -0.0002 0.0001 0.0001 0.0000 -0.0003 0.0007 0.0007 0.0015 0.0017 0.0024 0.0006 0.0082 0.0044 0.0011 0.0049
MP3=FULL         0.0003   0.0011                
Coupled Cluster CCSD(T)=FULL         0.0004               0.0046   0.0054
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVQZ

behq1.gif