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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For TiH atoms 1 and 2

For TiH (Titanium monohydride)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ
Moller Plesset perturbation MP2=FULL 0.0005 -0.0004 -0.0004 0.0051   0.0237 0.0335   0.0381 0.0271 0.0390 0.0387 0.0584 0.0555 0.0487 0.0575 0.0620
MP3=FULL         0.0103   0.0213       0.0228 0.0280 0.0374        
MP4=FULL   -0.0043     0.0108       0.0252     0.0292 0.0445   0.0383 0.0439  
B2PLYP=FULL -0.0001 -0.0007 -0.0007 0.0013 0.0064 0.0086 0.0120 0.0107 0.0123 0.0100 0.0132 0.0136 0.0209   0.0170 0.0206  
Quadratic configuration interaction QCISD(T)=FULL         0.0127             0.0333 0.0497   0.0438 0.0503  
Coupled Cluster CCSD=FULL         0.0137           0.0309 0.0326 0.0466 0.0441 0.0422 0.0457 0.0503
CCSD(T)=FULL         0.0118           0.0279 0.0323 0.0489 0.0464 0.0426 0.0492 0.0518
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ

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