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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For SO+ atoms 1 and 2

For SO+ (sulfur monoxide cation)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0002 -0.0000 0.0002 0.0001 -0.0039 0.0011 0.0011 -0.0003 0.0005 0.0039 0.0023 0.0005 0.0009 0.0005 0.0022 0.0017 0.0048 0.0029 0.0052 0.0021 0.0055
MP3=FULL         0.0008   0.0068       0.0017 0.0004 0.0007 0.0026           0.0016 0.0043
MP4=FULL         0.0014       0.0006   0.0020   0.0012 0.0035   0.0021 0.0054     0.0025 0.0060
B2PLYP=FULL 0.0000 -0.0000 0.0000 0.0000 0.0002 0.0002 0.0002 0.0001 0.0001 0.0009 0.0005 0.0001 0.0001 0.0007   0.0002 0.0010     0.0002 0.0011
Coupled Cluster CCSD=FULL         0.0011         0.0033 0.0023 0.0007 0.0010 0.0030 0.0022 0.0017 0.0045 0.0028   0.0020 0.0050
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z daug-cc-pVDZ daug-cc-pVTZ

soq1.gif