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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For GeF atoms 1 and 2

For GeF (Germanium monofluoride)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0016 0.0011 -0.0007 0.0227 0.0273 0.0273 0.0291 0.0332 0.0332 0.0592 0.0495 -0.0005 0.0006 0.0034 0.0102 0.0015 0.0076 0.0144 0.0024 0.0124
MP3=FULL         0.0247   0.0217                          
B2PLYP=FULL 0.0011 0.0004 -0.0001 0.0143 0.0125 0.0125 0.0140 0.0155 0.0155 0.0246 0.0229 -0.0002 0.0002 0.0012   0.0005 0.0023   0.0008 0.0041
Quadratic configuration interaction QCISD(T)=FULL         0.0272           0.0517   0.0007 0.0032   0.0014 0.0067   0.0023 0.0122
Coupled Cluster CCSD=FULL         0.0264         0.0597 0.0514 -0.0005 0.0006 0.0030 0.0084 0.0013 0.0063 0.0115 0.0021 0.0118
CCSD(T)=FULL         0.0271           0.0517 -0.0005 0.0007 0.0038 0.0082 0.0014 0.0070 0.0119 0.0023 0.0122
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ

gefq1.gif