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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For BrO atoms 1 and 2

For BrO (Bromine monoxide)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0001 0.0003 0.0002 0.0008 0.0025 0.0025 0.0028 0.0005 0.0005 0.0117 0.0043 0.0000 0.0010 0.0044 0.0024 0.0022 0.0079 0.0049 0.0026 0.0115
MP3=FULL         0.0046   0.0108         -0.0000 0.0009 0.0035            
MP4=FULL   -0.0000     0.0025       0.0006       0.0010 0.0042   0.0022 0.0077      
B2PLYP=FULL 0.0000 0.0001 0.0001 0.0005 0.0008 0.0008 0.0009 0.0001 0.0001 0.0030 0.0009 0.0000 0.0004 0.0011   0.0007 0.0025   0.0009 0.0028
Quadratic configuration interaction QCISD(T)=FULL         0.0032           0.0034   0.0015 0.0042   0.0025 0.0080   0.0032 0.0110
Coupled Cluster CCSD=FULL         0.0030         0.0094 0.0038 0.0006 0.0016 0.0041 0.0028 0.0026 0.0073 0.0049 0.0030 0.0101
CCSD(T)=FULL         0.0033           0.0033 0.0003 0.0015 0.0039 0.0028 0.0026 0.0073 0.0034 0.0030 0.0109
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ

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