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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For HCl- atoms 1 and 2

For HCl- (hydrogen chloride anion)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0000 0.0117 0.0173 0.0209 0.0361 0.0214 0.0876 0.0228 0.0135 0.0280 0.0049 0.0040 0.0043 0.0138 0.0118 0.0022 0.0050 0.0020 0.0151 0.0014 0.0032
MP3=FULL         -0.6072   -0.0320                            
B2PLYP=FULL 0.0000 0.0004 0.0007 0.0004 0.0005 0.0005 0.0010 0.0006 0.0010 0.0009 0.0013 0.0006 0.0004 0.0028   0.0009 0.0018     0.0004 0.0010
Quadratic configuration interaction QCISD(T)=FULL         0.0243           0.0042   0.0022 0.0104   0.0025 0.0053     0.0015 0.0031
Coupled Cluster CCSD=FULL         0.0203         0.0162 0.0028 0.0026 0.0022 0.0111 0.0065 0.0022 0.0056 0.0020   0.0015 0.0033
CCSD(T)=FULL         0.4066           0.0042 0.0031 0.0022 0.0105 0.0068 0.0025 0.0053     0.0015 0.0031
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(T+d)Z daug-cc-pVDZ daug-cc-pVTZ

hclq1.gif